FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2953203907> ?p ?o ?g. }

• W2953203907 endingPage "932" @default.
• W2953203907 startingPage "926" @default.
• W2953203907 abstract "In order to accomplish the selective synthesis of [60]fullerene bisadducts, the reactions of [60]fullerene with compounds in which two α,α‘-dibromo-o-xylene moieties were connected by an oligomethylene chain (n = 2−5) were investigated. By this method, only two isomers (cis-2- and cis-3-isomers) were selectively obtained when n = 2 and 3, while another isomer (e-isomer) was obtained when n = 5. When n = 4, a complex mixture of bisadducts was formed and has not been separated so far. cis-2-Bisadducts have been, for the first time, selectively obtained in the fullerene chemistry. The structures of bisadducts were determined on the basis of 1H, 13C NMR, IR, UV−vis, and mass spectroscopies. According to the NMR experiments, the symmetries of cis-2-, cis-3-, and e-isomers were concluded to be Cs, C2, and C1, respectively. Chiral cis-3- and e-bisadducts were successfully resolved into the respective enantiomers on a chiral HPLC column, although cis-2-bisadducts only gave a single peak. The UV−vis spectra of cis-2-, cis-3-, and e-bisadducts were remarkably different from one another. Specifically, the e-bisadducts showed a characteristic absorption peak around 420 nm. The cleavage of the oligomethylene chain produced the corresponding [60]fullerene derivatives possessing two phenol moieties. These compounds are applicable to further functionalization." @default.
• W2953203907 created "2019-06-27" @default.
• W2953203907 creator A5035471434 @default.
• W2953203907 creator A5047140062 @default.
• W2953203907 creator A5050742822 @default.
• W2953203907 creator A5058001856 @default.
• W2953203907 creator A5061442573 @default.
• W2953203907 creator A5082574625 @default.
• W2953203907 creator A5085412804 @default.
• W2953203907 date "1997-02-01" @default.
• W2953203907 modified "2023-10-16" @default.
• W2953203907 title "Selective Functionalization on [60]Fullerene Governed by Tether Length" @default.
• W2953203907 cites W1968948666 @default.
• W2953203907 cites W1976338080 @default.
• W2953203907 cites W2000356270 @default.
• W2953203907 cites W2005559284 @default.
• W2953203907 cites W2005688700 @default.
• W2953203907 cites W2013603217 @default.
• W2953203907 cites W2022152519 @default.
• W2953203907 cites W2025545401 @default.
• W2953203907 cites W2030398200 @default.
• W2953203907 cites W2033428802 @default.
• W2953203907 cites W2034442769 @default.
• W2953203907 cites W2040006466 @default.
• W2953203907 cites W2047478265 @default.
• W2953203907 cites W2048965446 @default.
• W2953203907 cites W2054087080 @default.
• W2953203907 cites W2062399031 @default.
• W2953203907 cites W2067681439 @default.
• W2953203907 cites W2071044628 @default.
• W2953203907 cites W2072492981 @default.
• W2953203907 cites W2083012275 @default.
• W2953203907 cites W2085905694 @default.
• W2953203907 cites W2093496757 @default.
• W2953203907 cites W2098677114 @default.
• W2953203907 cites W2121154500 @default.
• W2953203907 cites W2143263582 @default.
• W2953203907 cites W2147321097 @default.
• W2953203907 cites W2169334861 @default.
• W2953203907 cites W2949310029 @default.
• W2953203907 cites W2952609915 @default.
• W2953203907 cites W4210994512 @default.
• W2953203907 cites W49216827 @default.
• W2953203907 doi "https://doi.org/10.1021/ja960873m" @default.
• W2953203907 hasPublicationYear "1997" @default.
• W2953203907 type Work @default.
• W2953203907 sameAs 2953203907 @default.
• W2953203907 citedByCount "81" @default.
• W2953203907 countsByYear W29532039072012 @default.
• W2953203907 countsByYear W29532039072013 @default.
• W2953203907 countsByYear W29532039072014 @default.
• W2953203907 countsByYear W29532039072016 @default.
• W2953203907 countsByYear W29532039072017 @default.
• W2953203907 countsByYear W29532039072019 @default.
• W2953203907 countsByYear W29532039072021 @default.
• W2953203907 crossrefType "journal-article" @default.
• W2953203907 hasAuthorship W2953203907A5035471434 @default.
• W2953203907 hasAuthorship W2953203907A5047140062 @default.
• W2953203907 hasAuthorship W2953203907A5050742822 @default.
• W2953203907 hasAuthorship W2953203907A5058001856 @default.
• W2953203907 hasAuthorship W2953203907A5061442573 @default.
• W2953203907 hasAuthorship W2953203907A5082574625 @default.
• W2953203907 hasAuthorship W2953203907A5085412804 @default.
• W2953203907 hasConcept C103319777 @default.
• W2953203907 hasConcept C115537861 @default.
• W2953203907 hasConcept C147597530 @default.
• W2953203907 hasConcept C147789679 @default.
• W2953203907 hasConcept C162862793 @default.
• W2953203907 hasConcept C163111631 @default.
• W2953203907 hasConcept C178790620 @default.
• W2953203907 hasConcept C185592680 @default.
• W2953203907 hasConcept C486523 @default.
• W2953203907 hasConcept C71240020 @default.
• W2953203907 hasConcept C82188760 @default.
• W2953203907 hasConceptScore W2953203907C103319777 @default.
• W2953203907 hasConceptScore W2953203907C115537861 @default.
• W2953203907 hasConceptScore W2953203907C147597530 @default.
• W2953203907 hasConceptScore W2953203907C147789679 @default.
• W2953203907 hasConceptScore W2953203907C162862793 @default.
• W2953203907 hasConceptScore W2953203907C163111631 @default.
• W2953203907 hasConceptScore W2953203907C178790620 @default.
• W2953203907 hasConceptScore W2953203907C185592680 @default.
• W2953203907 hasConceptScore W2953203907C486523 @default.
• W2953203907 hasConceptScore W2953203907C71240020 @default.
• W2953203907 hasConceptScore W2953203907C82188760 @default.
• W2953203907 hasIssue "5" @default.
• W2953203907 hasLocation W29532039071 @default.
• W2953203907 hasOpenAccess W2953203907 @default.
• W2953203907 hasPrimaryLocation W29532039071 @default.
• W2953203907 hasRelatedWork W1541515203 @default.
• W2953203907 hasRelatedWork W1970078414 @default.
• W2953203907 hasRelatedWork W2043526535 @default.
• W2953203907 hasRelatedWork W2156065921 @default.
• W2953203907 hasRelatedWork W2318375508 @default.
• W2953203907 hasRelatedWork W2384015469 @default.
• W2953203907 hasRelatedWork W2951208626 @default.
• W2953203907 hasRelatedWork W2951442564 @default.
• W2953203907 hasRelatedWork W4211027341 @default.

• next