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- W2953204195 abstract "The Diels-Alder reactions of ethyl α-bromoacrylate 1 with open-chain dienes 2 were conducted under thermal or Lewis acid-catalysis conditions. In most cases, the cyclic adducts of 1-bromocyclohex-3-enecarboxylates 3 were formed in high yields with good regio- and stereoselectivity. Subsequent E2-elimination by treatment with DBU provided the corresponding 1,3- or 1,4-cyclohexadienecarboxylates depending on the relative configuration of the products. Starting from myrcene (7-methyl-3-methyleneocta-1,6-diene) the reaction sequence afforded the ester precursor of Georgywood with good yields." @default.
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- W2953204195 date "2010-04-29" @default.
- W2953204195 modified "2023-09-25" @default.
- W2953204195 title "Diels-Alder Reactions of Ethyl α-Bromoacrylate with Open-chain Dienes-Synthesis of Ethyl 1,3-/ 1,4-Cyclohexadienecarboxylates" @default.
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- W2953204195 doi "https://doi.org/10.1002/cjoc.201090121" @default.
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