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• W2953204343 abstract "Both 6-chloro-2-iodo-9-isopropylpurine (1) and 2-chloro-6-iodo-9-benzylpurine (4) undergo a selective I/Mg exchange reaction with iPrMgCl at −80 °C. The reaction course at 0 °C is different. Magnesiation of 1 proceeds with the migration of magnesium to the 8 position of the purine nuclei. In the case of 4, substitution of iodine with an alkyl group from the Grignard reagent accompanied with a Cl/Mg exchange reaction takes place, and 6-alkyl-2-magnesiated purines (9) are formed. Thus prepared Grignard reagents afford the corresponding alcohols by the reaction with aldehydes." @default.
• W2953204343 created "2019-06-27" @default.
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• W2953204343 date "2006-03-01" @default.
• W2953204343 modified "2023-09-27" @default.
• W2953204343 title "Selective Magnesiation of Chloro-iodopurines: An Efficient Approach to New Purine Derivatives" @default.
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• W2953204343 doi "https://doi.org/10.1021/ol053013w" @default.
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