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- W2953204509 abstract "The dissolution rates of active homogeneous metallic glasses are greater than those of homogeneous crystals of the same composition. If thermodynamically unstable homogeneous crystals are first formed, their later disintegration into a heterogeneous alloy usually results in an increase of the dissolution rate which may exceed the dissolution rate of the glass. Several examples of this behavior are discussed. A general theory for the dissolution rate of active alloys was developed and tested experimentally with metallic glasses offering the advantage that the composition can be changed in wide limits without changing the structure. In ideal cases the rate constants for the dissolution of the components are independent of their concentration in the alloy. Usually the total dissolution rates were faster than in the ideal case. The behavior is explained in terms of the atomistic structure and of the composition of the alloy surface. The effect of some components on the passivity of metallic glasses is considered." @default.
- W2953204509 created "2019-06-27" @default.
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- W2953204509 date "1989-05-02" @default.
- W2953204509 modified "2023-09-25" @default.
- W2953204509 title "ChemInform Abstract: Kinetics and Mechanisms of the Anodic Dissolution of Metallic Glasses." @default.
- W2953204509 cites W2006946150 @default.
- W2953204509 doi "https://doi.org/10.1002/chin.198918023" @default.
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