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- W2953209898 abstract "Spectroscopic evidence for I2S2O32- and IS2O3-, postulated as intermediates in the iodine{thiosulfate reaction, has been obtained by using the technique of pulse radiolysis to oxidize iodide to I3- in the presence of thiosulfate. The spectra show blue shifts with respect to I3- and I2 respectively. The kinetics of the reaction over a range of concentrations different from those reported by Scheper and Margerum have also been studied and further evidence for their quantitative scheme has been obtained; a change predicted by their model, but not detected by them, in kinetic order in S2O32- at low thiosulfate and high iodide concentrations has been found." @default.
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- W2953209898 date "1997-01-01" @default.
- W2953209898 modified "2023-09-26" @default.
- W2953209898 title "The Iodine—Thiosulfate Reaction: a Pulse-Radiolysis Study and Spectrophotometric Evidence for the Intermediates I2S2O32- and IS203-." @default.
- W2953209898 doi "https://doi.org/10.1071/c97001" @default.
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