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- W2953210242 endingPage "10508" @default.
- W2953210242 startingPage "10499" @default.
- W2953210242 abstract "Abstract Visible light irradiation is found to enhance the reducing ability of samarium diiodide (SmI2) dramatically. Organic halides (RCl, RBr, RI) and chalcogenides (RSPh, RSePh, RTePh) are smoothly reduced to the corresponding hydrocarbons by using this SmI2–hv system. The photoactivation can be also applied to ytterbium diiodide (YbI2) successfully. When the reduction of alkyl chlorides (RCl) by using the SmI2–hv system is conducted under the pressure of carbon monoxide, unsymmetric ketones (RC(O)CH2R) are obtained as carbonylating products. A mechanistic pathway may involve the formation of acylsamarium species (RC(O)SmI2), which undergo dimerization, followed by reduction with SmI2, leading to the unsymmetric ketones." @default.
- W2953210242 created "2019-06-27" @default.
- W2953210242 creator A5010555718 @default.
- W2953210242 creator A5034342075 @default.
- W2953210242 creator A5036244962 @default.
- W2953210242 creator A5059642294 @default.
- W2953210242 date "2003-12-01" @default.
- W2953210242 modified "2023-10-02" @default.
- W2953210242 title "A novel photoinduced reduction system of low-valent samarium species: reduction of organic halides and chalcogenides, and its application to carbonylation with carbon monoxide" @default.
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