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- W2953218045 abstract "The synthesis, crystal structure, crystal growth, and characterization of a new noncentrosymmetric rare-earth borate BiSr(3)(YO)(3)(BO(3))(4) are reported. BiSr(3)(YO)(3)(BO(3))(4) belongs to gaudefroyite type of structure and crystallizes in the polar hexagonal space group P6(3) (no. 173) with a = 10.6975(16) Å and c = 6.7222(12) Å. In the structure, the YO(7) polyhedra share edges to form an one-dimensional chain along the [001] direction. These chains are interconnected by the BO(3) group to construct a three-dimensional framework, leaving two kinds of channels for Bi atoms and Sr atoms together with BO(3) groups, respectively. On the basis of the powder second-harmonic generation (SHG) measurement, BiSr(3)(YO)(3)(BO(3))(4) belongs to the phase-matchable class with a SHG response of about 3 × KDP." @default.
- W2953218045 created "2019-06-27" @default.
- W2953218045 creator A5048951405 @default.
- W2953218045 creator A5065912071 @default.
- W2953218045 date "2011-12-14" @default.
- W2953218045 modified "2023-09-27" @default.
- W2953218045 title "BiSr<sub>3</sub>(YO)<sub>3</sub>(BO<sub>3</sub>)<sub>4</sub>: A New Gaudefroyite-Type Rare-Earth Borate with Moderate SHG Response" @default.
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- W2953218045 doi "https://doi.org/10.1021/ic201858x" @default.
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