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- W2953219651 abstract "An ultrasound-assisted convenient method was developed for the conversion of toxic methoxylated cis-isomer of arylalkenes into its hypolipidemic active trans-isomer. Treatment of cis-isomer or mixture of all three isomers (1a–1j) with ammonium formate and 10% Pd/C gave arylalkanes (2a–2j), which upon oxidation with DDQ in anhydrous dioxane containing a little amount of silica gel, provided (E)-arylalkenes (3a–3g) in 42–72% yield depending upon the substituents attached at the aryl ring. The same method, upon addition of a few drops of water, provided hypolipidemic active arylalkanones (3h–3j) in 59–65% yield." @default.
- W2953219651 created "2019-06-27" @default.
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- W2953219651 creator A5039932631 @default.
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- W2953219651 date "2005-03-01" @default.
- W2953219651 modified "2023-09-27" @default.
- W2953219651 title "Ultrasound-assisted convenient synthesis of hypolipidemic active natural methoxylated (E)-arylalkenes and arylalkanones" @default.
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- W2953219651 doi "https://doi.org/10.1016/j.tet.2005.01.071" @default.
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