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- W2953220281 abstract "We presented a Lewis acid-catalyzed nucleophilic ring opening of methylenecyclopropane (MCP) 1,1-diesters with propargyl alcohols. Unlike the proximal-bond cleavage mode observed in cases of unactivated MCPs, the intrinsic characteristic of MCP 1,1-diesters gave a regiospecific distal-bond cleavage under attack of propargyl alcohols as nucleophiles. By combining a subsequent intramolecular Conia-ene reaction, 3,5-dimethylenetetrahydropyrans could be obtained in either a stepwise or a one-pot strategy." @default.
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- W2953220281 date "2011-05-12" @default.
- W2953220281 modified "2023-09-25" @default.
- W2953220281 title "ChemInform Abstract: Lewis Acid-Catalyzed Nucleophilic Ring-Opening/Intramolecular Conia-Ene Reactions of Methylenecyclopropane 1,1-Diesters with Propargyl Alcohols." @default.
- W2953220281 cites W2079812001 @default.
- W2953220281 doi "https://doi.org/10.1002/chin.201123124" @default.
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