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- W2953231490 abstract "When NO- 3 is electrochemically oxidized in the presence of a variety of terminal and 1,2-disubstituted olefins 1 in a mixed solvent system (MeCN: H2O: Et2O = 10: 2:1), a radical NO3 is generated from NO- 3 and nitrate esters 3 are formed by a new coupling reaction of the olefin with the radical. The products 3 can be further transformed into the corresponding alcohols 4 and alkyl iodides 5. Under the same reaction conditions, 1,1-di- and 1,1,2-trisubstituted olefins 6 do not give nitrate esters but afford oxazoline derivatives 7. (1S,5S)-(-)-ß-Pinene (13) is diastereoselectively transformed into (1S,2R,5S)-(-)-myrtanol (14) by this technique." @default.
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- W2953231490 date "1994-01-01" @default.
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- W2953231490 title "Electroorganic Chemistry; 145:<sup>1</sup>Coupling Reaction of an Olefin with a Radical NO<sub>3</sub> <sup>·</sup>Generated by Anodic Oxidation of NO<sub>3</sub> <sup>-</sup>" @default.
- W2953231490 doi "https://doi.org/10.1055/s-1994-25594" @default.
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