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- W2953237212 abstract "Abstract The first organocatalytic asymmetric aldol reaction of isocyanoesters with various β,γ-unsaturated α-ketoesters has been described. Using cinchona alkaloid-derived bifunctional thiourea as the catalyst, chiral β-hydroxy-α-amino acid derivatives can be obtained in excellent yields and enantioselectivities (up to 95% yield and 92% ee) after acidic hydrolysis. This protocol provides a straightforward method to access multiple substituted β-hydroxy-α-amino acid derivatives with high enantiomeric purity." @default.
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- W2953237212 date "2014-04-01" @default.
- W2953237212 modified "2023-10-01" @default.
- W2953237212 title "Asymmetric synthesis of chiral β-hydroxy-α-amino acid derivatives by organocatalytic aldol reactions of isocyanoesters with β,γ-unsaturated α-ketoesters" @default.
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- W2953237212 doi "https://doi.org/10.1016/j.tetasy.2014.03.014" @default.
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