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- W2953238785 abstract "Abstract A novel, stereo selective synthesis of (−)-cytoxazone 1a and stereoselective synthesis of (+)-5-epi-cytoxazone 1b were achieved via stereoselective Grignard addition of vinylmagnesium bromide on N-Boc al ehyde obtained from p-hydroxy-d-phenylglycine 2 followed by cyclization of N-Boc alcohol 6, ozonolysis and reduction to get (+)-5-epi-cytoxazone. Compound 6 underwent mitsunobu conditions, deprotection of ester followed by cyclization of N-Boc alcohol to get (−)-cytoxazone." @default.
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- W2953238785 date "2003-01-08" @default.
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- W2953238785 title "Stereoselective Synthesis of (−)-Cytoxazone and (+)-5-Epi-cytoxazone" @default.
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- W2953238785 doi "https://doi.org/10.1081/scc-120022181" @default.
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