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- W2953245912 abstract "The reaction of brominated isophorone compounds with sodium methoxide in methanol has been investigated and mechanisms for these reactions are discussed. 4-Bromoisophorone gave exclusively 2-methoxyisophorone, while 2,4,6-tribromo- and 2,4,6,6-tetrabromo-3-bromomethyl-2-cyclohexenone afforded 2,4-cyclohexadienone compounds.However, the reaction of 2,4,6- and 2,6,6-tribromo-3-dibromomethyl-5,5-dimethyl-2-cyclohexenone took a total different way with formation of resp. a bicyclo compound and Favorskii rearrangement products.These results were rationalized in terms of zwitterionic species instead of the classical nucleophilic substitution." @default.
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- W2953245912 date "1975-08-12" @default.
- W2953245912 modified "2023-09-27" @default.
- W2953245912 title "ChemInform Abstract: NUCLEOPHILIC SUBSTITUTION OF BROMINATED ISOPHORONE COMPOUNDS VIA ZWITTERIONIC INTERMEDIATES" @default.
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- W2953245912 doi "https://doi.org/10.1002/chin.197532200" @default.
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