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- W2953249938 abstract "A novel and efficient I2/DMSO mediated metal-free strategy is presented for the direct C–C bond cleavage of aryl-/heteroaryl- or aliphatic α-ketoaldehydes by C2-decarbonylation and C1-carbonyl oxidation to give the corresponding carboxylic acids followed by esterification in one pot, offering excellent yields in both the steps. Here, DMSO acts as the oxygen source/oxidant and this reaction works very well under both conventional heating and microwave irradiation. This is a very simple and convenient protocol." @default.
- W2953249938 created "2019-06-27" @default.
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- W2953249938 date "2015-10-27" @default.
- W2953249938 modified "2023-09-27" @default.
- W2953249938 title "ChemInform Abstract: DMSO/I2Mediated C-C Bond Cleavage of α-Ketoaldehydes Followed by C-O Bond Formation: A Metal-Free Approach for One-Pot Esterification." @default.
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- W2953249938 doi "https://doi.org/10.1002/chin.201546033" @default.
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