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- W2953266525 abstract "Optically active heterocyclic allyl sulphides 1–7 react with organomagnesium compounds in the presence of CuBr to afford optically active alkenes in good yields and very high γ-selectivity. The regioselectivity depends on the solvent as well on the CuBr: allylic sulphide ratio. The heterocyclic nucleus imparts asymmetric induction in the range of 50–98% ee. The regio- and enantio-selectivity of these reactions would be related to the coordination exerted by the heterocyclic nitrogen toward the copper organyl." @default.
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- W2953266525 date "1996-08-01" @default.
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- W2953266525 title "Copper-mediated regio- and enantio-selective cross-coupling of heterocyclic allyl sulphides with organomagnesium compounds: A case of 1,7-relative stereogenesis" @default.
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- W2953266525 doi "https://doi.org/10.1016/0040-4020(96)00601-1" @default.
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