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- W2953271806 abstract "Phosphorus compounds that contain silicon-nitrogen functional groups have a very rich derivative chemistry. The wide variety of reactions that can occur at phosphorus in combination with facile cleavage of the Si-N bond makes them useful precursors to many types of cyclic and polymeric P-N systems. We report here on (a) the synthesis and reactivity of (silylamino)phosphines, including some new systems that contain 4-aryl functional groups on phosphorus, and (b) the synthesis and characterization of two new types of (silylanilino)phosphines that contain either a 4-aryl functional group on nitrogen or a phenylene ring between nitrogen and phosphorus. These anilino derivatives are potential precursors to poly(phenylenephosphazenes), a new class of inorganic-organic hybrid polymers in which phosphazene (R2P=N) and phenylene (C6H4) units alternate along the backbone." @default.
- W2953271806 created "2019-06-27" @default.
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- W2953271806 date "2005-12-01" @default.
- W2953271806 modified "2023-10-16" @default.
- W2953271806 title "Synthesis and Reactivity of (Silylamino)- and (Silylanilino)phosphines" @default.
- W2953271806 doi "https://doi.org/10.1021/bk-2005-0917.ch023" @default.
- W2953271806 hasPublicationYear "2005" @default.
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