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- W2953272203 abstract "Catalyst-controlled divergent intermolecular cycloadditions of vinylaziridines with alkynes have been developed. By using [Rh(NBD)2]BF4 as the catalyst, a [3 + 2] cycloaddition reaction was achieved with broad substrate scope and high stereoselectivity under mild reaction conditions. Moreover, the chirality of vinylaziridines can be completely transferred to the [3 + 2] cycloadducts. When the catalyst was changed to [Rh(η(6)-C10H8) (COD)]SbF6, the alternative [5 + 2] cycloadducts were selectively formed under otherwise identical conditions." @default.
- W2953272203 created "2019-06-27" @default.
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- W2953272203 date "2016-07-01" @default.
- W2953272203 modified "2023-09-27" @default.
- W2953272203 title "ChemInform Abstract: The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes." @default.
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- W2953272203 doi "https://doi.org/10.1002/chin.201633036" @default.
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