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- W2953277017 abstract "A new, catalytic enantioselective route to 3-arylindan-1-ones, versatile intermediates for the synthesis of a number of bioactive and pharmaceutically interesting molecules, was developed by exploiting the chiral dirhodium(II) complex-catalyzed intramolecular C-H insertion reaction of α-diazo-β-ketoesters as a key step. Dirhodium(II) tetrakis]N-phthaloyl-(S)-tert-leucinate], Rh 2 (S-PTTL) 4 , proved to be the catalyst of choice for this process, providing enantioselectivities of up to 72% ee." @default.
- W2953277017 created "2019-06-27" @default.
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- W2953277017 date "2006-01-01" @default.
- W2953277017 modified "2023-10-09" @default.
- W2953277017 title "Enantioselective Synthesis of 3-Arylindan-1-ones via Intramolecular C-H Insertion Reactions of α-Diazo-β-Ketoesters Catalyzed by Chiral Dirhodium(II) Carboxylates" @default.
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- W2953277017 doi "https://doi.org/10.3987/com-06-s(w)58" @default.
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