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- W2953280070 abstract "Abstract Pentafluorophenol acts as an efficient proton source for sodium borohydride reductions in diethyl ether containing methanol. This system allows for the regioselective reduction of α,β-unsaturated carbonyl compounds to the corresponding allylic alcohols in high yield. Use of either 1-hexene or N,N,N',N'-tetramethylethylenediamine as borane scavengers moderately improved the regioselectivity of this reaction. Fortunately, sodium trispentafluorophenoxyborohydride, generated in situ, gave regiospecific 1,2-reduction of α,β,-unsaturated carbonyl compounds." @default.
- W2953280070 created "2019-06-27" @default.
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- W2953280070 date "2010-08-18" @default.
- W2953280070 modified "2023-09-26" @default.
- W2953280070 title "ChemInform Abstract: Reduction of α,β-Unsaturated Carbonyl Compounds with Sodium Borohydride in the Diethyl Ether/Methanol/Pentafluorophenol Solvent System. Use of N,N,N′,N′-Tetramethylethylenediamine and 1-Hexene as Borane Scavengers." @default.
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- W2953280070 doi "https://doi.org/10.1002/chin.199509076" @default.
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