Matches in SemOpenAlex for { <https://semopenalex.org/work/W2953282611> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2953282611 abstract "Under the influence of a chiral bidentate diphosphine ligand, the Pd-catalyzed asymmetric cross-coupling of allylboron reagents and allylic electrophiles establishes 1,5-dienes with adjacent stereocenters in high regio- and stereoselectivity. A mechanistic study of the coupling utilizing reaction calorimetry and density functional theory analysis suggests that the reaction operates through an inner-sphere 3,3′-reductive elimination pathway, which is both rate-defining and stereodefining. Coupled with optimized reaction conditions, this mechanistic detail is used to expand the scope of allyl–allyl couplings to allow the generation of 1,5-dienes with tertiary centers adjacent to quaternary centers as well as a unique set of cyclic structures." @default.
- W2953282611 created "2019-06-27" @default.
- W2953282611 creator A5026870258 @default.
- W2953282611 creator A5051400510 @default.
- W2953282611 date "2014-11-20" @default.
- W2953282611 modified "2023-09-27" @default.
- W2953282611 title "ChemInform Abstract: Congested C-C Bonds by Pd-Catalyzed Enantioselective Allyl-Allyl Cross-Coupling, a Mechanism-Guided Solution." @default.
- W2953282611 cites W2332002457 @default.
- W2953282611 doi "https://doi.org/10.1002/chin.201449047" @default.
- W2953282611 hasPublicationYear "2014" @default.
- W2953282611 type Work @default.
- W2953282611 sameAs 2953282611 @default.
- W2953282611 citedByCount "0" @default.
- W2953282611 crossrefType "journal-article" @default.
- W2953282611 hasAuthorship W2953282611A5026870258 @default.
- W2953282611 hasAuthorship W2953282611A5051400510 @default.
- W2953282611 hasConcept C115624301 @default.
- W2953282611 hasConcept C116569031 @default.
- W2953282611 hasConcept C120095180 @default.
- W2953282611 hasConcept C134195300 @default.
- W2953282611 hasConcept C146686406 @default.
- W2953282611 hasConcept C155647269 @default.
- W2953282611 hasConcept C161790260 @default.
- W2953282611 hasConcept C170493617 @default.
- W2953282611 hasConcept C178516000 @default.
- W2953282611 hasConcept C178790620 @default.
- W2953282611 hasConcept C181647583 @default.
- W2953282611 hasConcept C185592680 @default.
- W2953282611 hasConcept C21951064 @default.
- W2953282611 hasConcept C2778815869 @default.
- W2953282611 hasConcept C40875361 @default.
- W2953282611 hasConcept C50027330 @default.
- W2953282611 hasConcept C55493867 @default.
- W2953282611 hasConcept C71240020 @default.
- W2953282611 hasConceptScore W2953282611C115624301 @default.
- W2953282611 hasConceptScore W2953282611C116569031 @default.
- W2953282611 hasConceptScore W2953282611C120095180 @default.
- W2953282611 hasConceptScore W2953282611C134195300 @default.
- W2953282611 hasConceptScore W2953282611C146686406 @default.
- W2953282611 hasConceptScore W2953282611C155647269 @default.
- W2953282611 hasConceptScore W2953282611C161790260 @default.
- W2953282611 hasConceptScore W2953282611C170493617 @default.
- W2953282611 hasConceptScore W2953282611C178516000 @default.
- W2953282611 hasConceptScore W2953282611C178790620 @default.
- W2953282611 hasConceptScore W2953282611C181647583 @default.
- W2953282611 hasConceptScore W2953282611C185592680 @default.
- W2953282611 hasConceptScore W2953282611C21951064 @default.
- W2953282611 hasConceptScore W2953282611C2778815869 @default.
- W2953282611 hasConceptScore W2953282611C40875361 @default.
- W2953282611 hasConceptScore W2953282611C50027330 @default.
- W2953282611 hasConceptScore W2953282611C55493867 @default.
- W2953282611 hasConceptScore W2953282611C71240020 @default.
- W2953282611 hasLocation W29532826111 @default.
- W2953282611 hasOpenAccess W2953282611 @default.
- W2953282611 hasPrimaryLocation W29532826111 @default.
- W2953282611 hasRelatedWork W1987733084 @default.
- W2953282611 hasRelatedWork W2066936401 @default.
- W2953282611 hasRelatedWork W2332002457 @default.
- W2953282611 hasRelatedWork W2342131385 @default.
- W2953282611 hasRelatedWork W2949221192 @default.
- W2953282611 hasRelatedWork W2949411518 @default.
- W2953282611 hasRelatedWork W2949538298 @default.
- W2953282611 hasRelatedWork W2949991137 @default.
- W2953282611 hasRelatedWork W2950123236 @default.
- W2953282611 hasRelatedWork W2950280559 @default.
- W2953282611 hasRelatedWork W2950283033 @default.
- W2953282611 hasRelatedWork W2950853212 @default.
- W2953282611 hasRelatedWork W2951010797 @default.
- W2953282611 hasRelatedWork W2951209552 @default.
- W2953282611 hasRelatedWork W2952058402 @default.
- W2953282611 hasRelatedWork W2952070261 @default.
- W2953282611 hasRelatedWork W2953105505 @default.
- W2953282611 hasRelatedWork W2953277815 @default.
- W2953282611 hasRelatedWork W3090256648 @default.
- W2953282611 hasRelatedWork W627665150 @default.
- W2953282611 isParatext "false" @default.
- W2953282611 isRetracted "false" @default.
- W2953282611 magId "2953282611" @default.
- W2953282611 workType "article" @default.