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• W2953286978 abstract "Dearomatization of arenes is a powerful strategy for the preparation of functionalized cyclic olefins. Phenol oxidation can be exploited as a dearomatization tactic to produce cyclohexa-2,4-dienones. Iodine(III)-mediated oxidation of 2-alkyl- and 2-alkoxynaphthols was accomplished in the presence of an allylsilane or a silyl enol ether carbon-based nucleophile to furnish cyclohexa-2,4-dienone derivatives in moderate to good yields. This intermolecular carbon−carbon bond-forming reaction is particularly promising for the preparation of synthetically valuable naphthoid orthoquinols." @default.
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• W2953286978 date "1999-10-17" @default.
• W2953286978 modified "2023-10-18" @default.
• W2953286978 title "Oxidized Arenol Intermediates in Intermolecular Carbon−Carbon Bond Formation. Naphthoid Cyclohexa-2,4-dienones via Oxidative Nucleophilic Substitution" @default.
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• W2953286978 doi "https://doi.org/10.1021/ol9910363" @default.
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