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- W2953286985 abstract "The conversion of (+) -limonen-10-ol (7) into the key intermediate for the synthesis of carbacyclin (1), (+) - (1S, 2R, 3R, 5R) -3-acetoxy-2-methoxycarbony1-7-oxobicyclo [3.3.0] octane (2), is described. The cis-3, 4-disubstituted cyclopentanone prepared from 7 via a sequence of reactions involving Rh (I) -catalyzed cyclization could be converted to the 3-acetylbicyclo [3.3.0] oct-2-ene skeleton, which was subjected to 1, 4-addition reaction with CN-. The resulting cyano compound was transformed into the key intermediate 2 through appropriate modification of the substituents on the five-membered ring. This synthetic method provides a new route to carbacyclin." @default.
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- W2953286985 date "1987-11-24" @default.
- W2953286985 modified "2023-09-23" @default.
- W2953286985 title "ChemInform Abstract: Conversion of (+)-Limonen-10-ol to Bicyclo(3.3.0)octane Skeleton. Synthesis of a Key Intermediate for Carbacyclin." @default.
- W2953286985 cites W2078732948 @default.
- W2953286985 doi "https://doi.org/10.1002/chin.198747149" @default.
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