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- W2953287527 abstract "Abstract Measurements leading to the calculation of the standard thermodynamic properties in the gas phase for acridine, phenanthridine, and 7,8-benzoquinoline are reported. Thermochemical and thermophysical properties were determined by adiabatic heat-capacity calorimetry, comparative ebulliometry, inclined-piston manometry, and combustion calorimetry. Comparisons with literature values are presented and discussed. Results were used to calculate standard entropies, enthalpies, and Gibbs free energies of formation at selected temperatures to 500 K. Group-contribution methods were used to estimate the standard gas-phase entropy and enthalpy of formation at 400 K for the remaining two benzoquinolines: 5,6-benzoquinoline and 6,7-benzoquinoline. The relative stabilities of the compounds and comparisons with hydrocarbon analogues are discussed. A reaction scheme for the formation of the benzoquinolines is outlined and the mole fractions of the isomers are estimated for the reactions proceeding under thermodynamic control." @default.
- W2953287527 created "2019-06-27" @default.
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- W2953287527 date "1989-05-23" @default.
- W2953287527 modified "2023-09-27" @default.
- W2953287527 title "ChemInform Abstract: The Thermodynamic Properties of the Five Benzoquinolines." @default.
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- W2953287527 doi "https://doi.org/10.1002/chin.198921049" @default.
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