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- W2953287533 abstract "New chiral crotylsilanes that bear a (Z)-olefin geometry were synthesized in high enantiopurity. The reagents participate in [4 + 2]-annulations with aldehydes to give stereochemically complementary pyrans (relative to (E)-crotylsilanes) bearing 2,6-cis-5,6-cis and 2,6-trans-5,6-cis relationships of peripheral functionalities. A stereoselective synthesis of the C1−C13 fragment of bistramide A is also described highlighting this annulation strategy." @default.
- W2953287533 created "2019-06-27" @default.
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- W2953287533 date "2005-07-01" @default.
- W2953287533 modified "2023-09-25" @default.
- W2953287533 title "Synthesis and [4 + 2]-Annulation of Enantioenriched (Z)-Crotylsilanes: Preparation of the C1−C13 Fragment of Bistramide A" @default.
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- W2953287533 doi "https://doi.org/10.1021/ol050982i" @default.
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