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- W2953288852 abstract "A highly stereoselective synthesis of the C(13)−C(23) segment of tedanolide (1), an 18-membered macrolide isolated from the Caribbean sponge Tedania ignis, displaying significant cytotoxicity against KB and PS tumor cell lines, is described which involves two stereoselective epoxidations of regioisomeric trisubstituted double bonds and a stereospecific SN2‘ methylation reaction of a trans-γ,δ-epoxy-cis-α,β-unsaturated ester as the key steps." @default.
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- W2953288852 date "2005-05-13" @default.
- W2953288852 modified "2023-10-10" @default.
- W2953288852 title "Synthetic Studies of Tedanolide, a Marine Macrolide Displaying Potent Antitumor Activity. Stereoselective Synthesis of the C(13)−C(23) Segment" @default.
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- W2953288852 doi "https://doi.org/10.1021/ol050569a" @default.
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