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- W2953291271 abstract "Reaction of optically active alpha-oxazolidinonylallenylstannanes with oxiranes in the presence of BF3.OEt2 produced beta-hydroxypropargylamines with high syn diastereoselectivity and high enantioselectivity through an initial Lewis-acid-catalyzed rearrangement of the oxirane to the corresponding aldehyde via an alkyl, aryl, or hydride shift. This permits the use of readily available oxiranes as alternatives to aldehydes that are difficult to prepare and/or unstable." @default.
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- W2953291271 date "2005-07-07" @default.
- W2953291271 modified "2023-09-30" @default.
- W2953291271 title "Reaction of Optically Active α-Aminoallenylstannanes with Aldehydes Formed in Situ from the Lewis-Acid-Catalyzed Rearrangement of Epoxides" @default.
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- W2953291271 doi "https://doi.org/10.1021/jo050813b" @default.
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