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- W2953296819 abstract "Tri-substituted vinyl pinacol boronates, which are key reactive intermediates in a variety of transformations, are synthesized using ruthenium-catalyzed olefin cross-metathesis of α-substituted vinyl boronates and various alkenes. Cross-metathesis of 2-isopropenyl pinacol boronate proceeds with moderate yield and high Z-selectivity when sterically unhindered cross partners are used. Cross-metathesis of vinyl boronates that possess α-substitution larger than a methyl group is also achieved. Yield and Z-selectivity are lower in these cases, and the success of a cross-metathesis reaction is highly dependent on the steric bulk surrounding the double bond of the α-substituted vinyl boronate." @default.
- W2953296819 created "2019-06-27" @default.
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- W2953296819 date "2004-10-01" @default.
- W2953296819 modified "2023-10-06" @default.
- W2953296819 title "Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis" @default.
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- W2953296819 doi "https://doi.org/10.1016/j.tetlet.2004.08.069" @default.
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