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- W2953296850 abstract "Abstract Under the conditions of the Heck reaction, 9‐benzyl‐6‐iodopurine affords mainly the corresponding 6,6′‐dimer, the Heck product being formed only in low yield (≤12 %). With 7‐benzyl‐6‐iodopurine the dimerization is suppressed and the Heck product is obtained in 32–91 % yield. 9‐Substituted 6‐chloro‐2‐iodopurines react smoothly, giving 2‐alkenyl‐6‐chloropurines in 71–97 % isolated yields. The reaction proceeds with alkenes bearing electron‐withdrawing substituents (like CO 2 Bu, COCH 3 , CN) and Ph, while vinyl acetate and dodec‐1‐ene are unreactive. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
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- W2953296850 date "2008-05-27" @default.
- W2953296850 modified "2023-09-24" @default.
- W2953296850 title "Heck Reactions of 6- and 2-Halopurines" @default.
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- W2953296850 doi "https://doi.org/10.1002/ejoc.200800091" @default.
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