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- W2953306299 abstract "Abstract Stilbene may be synthesised with Z-selectivity from (α-bromobenzyl)benzyldiphenylphosphonium bromide by the action of amine bases. A series of stilbenes was synthesised by the action of N-bromosuccinimide and 2,2,6,6-tetramethylpiperidine directly upon dibenzyldiphenylphosphonium salts. The reaction, essentially a phosphonium analogue of the Ramberg-Backlund displays cis selectivity. The dibenzyldiphenylphosphonium salts were prepared by the one pot polymethylhydrosiloxane/titanium(IV) isopropoxide mediated reduction/alkylation of benzyldiphenylphosphine oxides." @default.
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- W2953306299 date "1998-12-01" @default.
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- W2953306299 title "The synthesis of alkenes via epi-phosphonium species: 2. A phosphorus Ramberg-Bäcklund reaction" @default.
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- W2953306299 doi "https://doi.org/10.1016/s0040-4020(98)00960-0" @default.
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