Matches in SemOpenAlex for { <https://semopenalex.org/work/W2953317416> ?p ?o ?g. }
- W2953317416 endingPage "1257" @default.
- W2953317416 startingPage "1248" @default.
- W2953317416 abstract "A mononuclear Ru(II)–N-heterocyclic carbene (NHC) complex [RuII(CO)2(κ2C,N-BIN)(H2O)Br][OTf] (OTf = trifluoromethane sulphonate) (1) has been synthesized in high-yield by the oxidative cleavage of the metal–metal singly-bonded diruthenium(I) precursor [Ru2(CO)4(CH3CN)6(OTf)2] with 1,8-naphthyridine functionalized NHC precursor 1-benzyl-3-(5,7-dimethyl-1,8-naphthyrid-2-yl)imidazolium bromide (BIN·HBr) at room temperature. Compound 1 catalyzes transfer hydrogenation of ketones to alcohols, and carbene-transfer from ethyl diazoacetate to a variety of substrates. It is shown to be an excellent catalyst for the insertion of carbene into the O–H and N–H bonds of alcohols and amines." @default.
- W2953317416 created "2019-06-27" @default.
- W2953317416 creator A5001515176 @default.
- W2953317416 creator A5010430402 @default.
- W2953317416 creator A5069247977 @default.
- W2953317416 creator A5073278712 @default.
- W2953317416 creator A5077769363 @default.
- W2953317416 date "2011-03-01" @default.
- W2953317416 modified "2023-09-23" @default.
- W2953317416 title "A RuII–N-heterocyclic carbene (NHC) complex from metal–metal singly bonded diruthenium(I) precursor: Synthesis, structure and catalytic evaluation" @default.
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