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- W2953319987 abstract "Abstract The structure and properties of the thermal decomposition products of Fe[Fe(CN) 5 NO] · x H 2 O (x = 5 ~ 6) have been studied by Mössbauer and FT-IR spectroscopy, X-ray diffraction, and conductivity measurements. The valence state and coordination environment of the iron ions change dramatically when the nitrosyl ligand is eliminated by heat-treatment under vacuum at 200 °C. The dark blue product obtained by heat-treatment under vacuum at 250 °C is characteristic of the mixed-valence state in Prussian blue analogues. The electrical conductivity of the dark blue product is higher by a factor of 103 than that of the starting material because of the mixed-valence state between Fe(III)[Fe(II)(CN) 5 ] and Fe(II)[Fe(III)(CN) 5 ]. Heat-treatment under vacuum at 350°C yields a new product Fe(II)[Fe(II)(CN) 4 ] the crystal structure of which is different from that of the starting material. The electrical conductivity of the decomposition product obtained at 350 °C is about 10 5 times higher than that of the starting material." @default.
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- W2953319987 date "2000-08-01" @default.
- W2953319987 modified "2023-09-25" @default.
- W2953319987 title "Thermal Decomposition of Prussian Blue Analogues of the Type Fe[Fe(CN)<sub>5</sub>NO]" @default.
- W2953319987 doi "https://doi.org/10.1515/znb-2000-0803" @default.
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