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- W2953323814 abstract "A convenient synthesis of 4,5-disubstituted 2H-thiopyran 1,1-dioxides is reported through a base induced process starting from eneyne sulfones. Except for strongly electron-withdrawing groups, the reaction tolerated a wide variety of substituents in the two aryl rings. This finding represents a major departure from the behaviour of the corresponding ethers. The reaction most probably proceeds through a 6π-electrocyclization from an in-situ-generated 1,3,5-trienyl sulfinate." @default.
- W2953323814 created "2019-06-27" @default.
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- W2953323814 date "2016-01-02" @default.
- W2953323814 modified "2023-09-27" @default.
- W2953323814 title "ChemInform Abstract: Base-Induced Cyclization of Propargyl Alkenylsulfones: A High-Yielding Synthesis of 4,5-Disubstituted 2H-Thiopyran 1,1-Dioxides." @default.
- W2953323814 cites W1956378742 @default.
- W2953323814 doi "https://doi.org/10.1002/chin.201602135" @default.
- W2953323814 hasPublicationYear "2016" @default.
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