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- W2953350391 abstract "Iron carbonyl species, prepared in situ at 25 °C through reduction of anhydrous FeCl3 with NaBH4 in the presence of carbon monoxide and acetic acid in THF, reacts with 1-alkynes at reflux temperature to give the corresponding benzoquinones after CuCl2·2H2O oxidation in moderate to good yields (51−80%). Also, these species upon CH3I treatment followed by reaction with 1-alkynes lead to the formation of the corresponding cyclobutenediones in moderate yields (30−37%) after CuCl2·2H2O oxidation." @default.
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- W2953350391 date "2000-05-11" @default.
- W2953350391 modified "2023-10-10" @default.
- W2953350391 title "Reactive Iron Carbonyl Species via Reduction of FeCl<sub>3</sub> with NaBH<sub>4</sub> in the Presence of CO: Conversion of 1-Alkynes to Benzoquinones and Cyclobutenediones" @default.
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- W2953350391 doi "https://doi.org/10.1021/om991017x" @default.
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