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- W2953373487 abstract "Abstract Peracetylated ester derivatives of N -acetyl neuraminic acid were reacted with hydrogen iodide in acetic acid to stereoselectively provide α-2-deoxy-2-hydrido analogs. The reaction proceeds through formation of an anomeric iodide which, in the presence of excess HI, is reduced to give an enol intermediate. Kinetic protonation of the intermediate enol gives a 3.4:1 α:β mixture of 2-deoxy-2-hydrido derivatives. Under thermodynamic conditions the α-anomer is formed exclusively." @default.
- W2953373487 created "2019-06-27" @default.
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- W2953373487 date "2010-08-03" @default.
- W2953373487 modified "2023-09-25" @default.
- W2953373487 title "ChemInform Abstract: HI/Acetic Acid Reduction of Peracetylated N-Acetyl Neuraminic Acid Esters to Stereoselectively Provide α-2-Deoxy-2-hydrido Derivatives." @default.
- W2953373487 cites W1986936914 @default.
- W2953373487 doi "https://doi.org/10.1002/chin.199747235" @default.
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