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- W2953374367 abstract "8-Thio-2‘-deoxyguanosine (SdG) is a useful analogue of the abundant promutagen 8-oxo-2‘-deoxyguanosine (OdG). Its synthesis and DNA incorporation using standard phosphoramidite chemistry is reported. To prevent oxidation during DNA synthesis, the sulfur was protected as a 2-(trimethylsilyl)ethyl sulfide. Subsequent treatment with TBAF yielded the desired 8-thiocarbonyl functionality. Melting studies with SdG revealed almost equal stabilities of SdG:dC and SdG:dA base pairs, lending insight into the base-pairing preferences of OdG." @default.
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- W2953374367 date "2004-09-22" @default.
- W2953374367 modified "2023-10-16" @default.
- W2953374367 title "Oligonucleotide Incorporation of 8-Thio-2‘-deoxyguanosine" @default.
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- W2953374367 doi "https://doi.org/10.1021/ol0484097" @default.
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