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- W2953449239 abstract "Abstract The reactivity of a mononuclear high‐spin iron(III)‐alkylperoxo intermediate [Fe III ( t ‐BuL Urea )(OOCm)(OH 2 )] 2+ ( 2 ), generated from [Fe II ( t ‐BuL Urea )(H 2 O)(OTf)](OTf) ( 1 ) [ t ‐BuL Urea =1,1′‐(((pyridin‐2‐ylmethyl)azanediyl)bis(ethane‐2,1‐diyl))bis(3‐(tert‐butyl)urea), OTf=trifluoromethanesulfonate] with cumyl hydroperoxide (CmOOH), toward the C−H and C=C bonds of hydrocarbons is reported. 2 oxygenates the strong C−H bonds of aliphatic substrates with high chemo‐ and stereoselectivity in the presence of 2,6‐lutidine. While 2 itself is a sluggish oxidant, 2,6‐lutidine assists the heterolytic O−O bond cleavage of the metal‐bound alkylperoxo, giving rise to a reactive metal‐based oxidant. The roles of the urea groups on the supporting ligand, and of the base, in directing the selective and catalytic oxygenation of hydrocarbon substrates by 2 are discussed." @default.
- W2953449239 created "2019-07-12" @default.
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- W2953449239 date "2019-08-01" @default.
- W2953449239 modified "2023-10-18" @default.
- W2953449239 title "Highly Selective and Catalytic Oxygenations of C−H and C=C Bonds by a Mononuclear Nonheme High‐Spin Iron(III)‐Alkylperoxo Species" @default.
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- W2953449239 doi "https://doi.org/10.1002/anie.201906978" @default.
- W2953449239 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31246329" @default.
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