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• W2953517326 endingPage "11438" @default.
• W2953517326 startingPage "11434" @default.
• W2953517326 abstract "The utilization of 5-hydroxymethyl furfural (HMF) as a renewable feedstock for polymer synthesis has not yet been achieved as it is structurally asymmetric and contains three active functional groups. Reported here is the unprecedented step-growth copolymerization of HMF and dihydrosilanes, through a coordination mechanism, to afford linear poly(silyl ether)s in the presence of B(C6F5)3 and the heteroscorpionate zinc hydride complex LZnH [L=(MePz)2CP(Ph)2NPh, MePz=3,5-dimethylpyrazolyl]. The adduct B(C6F5)3⋅⋅⋅H⋅⋅⋅Zn, confirmed by NMR spectroscopy and DFT calculations, plays a key role in the synergistic catalysis, where B(C6F5)3 activates ZnH and stabilizes the Zn+ active species, and the sterically bulky ZnH effectively inhibits (C6F5)3B from reacting with dihydrosilane to form (C6F5)3B-H-Si, which facilely initiates ring opening of furan. The mechanism was studied by DFT simulations." @default.
• W2953517326 created "2019-07-12" @default.
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• W2953517326 date "2019-08-12" @default.
• W2953517326 modified "2023-10-14" @default.
• W2953517326 title "Step‐Growth Coordination Polymerization of 5‐Hydroxymethyl Furfural with Dihydrosilanes: Synergistic Catalysis Using Heteroscopionate Zinc Hydride and B(C ₆ F ₅ ) ₃" @default.
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• W2953517326 doi "https://doi.org/10.1002/anie.201903800" @default.
• W2953517326 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31166066" @default.
• W2953517326 hasPublicationYear "2019" @default.
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