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- W2953554433 abstract "Abstract The structural puzzle of amipurimycin, a peptidyl nucleoside antibiotic, is solved by total synthesis and X‐ray diffraction analysis, with the originally proposed configurations at C3′ and C8′ inverted and those at C6′, C2′′, and C3′′ corrected. A similar structural revision of the relevant miharamycins is proposed via chemical transformations and then validated by X‐ray diffraction analysis. The miharamycins bear an unusual trans ‐fused dioxabicyclo[4.3.0]nonane sugar scaffold, which was previously assigned as being in the cis configuration." @default.
- W2953554433 created "2019-07-12" @default.
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- W2953554433 date "2019-07-01" @default.
- W2953554433 modified "2023-10-17" @default.
- W2953554433 title "The Miharamycins and Amipurimycin: their Structural Revision and the Total Synthesis of the Latter" @default.
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- W2953554433 doi "https://doi.org/10.1002/anie.201905723" @default.
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