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- W2953707911 abstract "We have investigated the crystal structure and magnetic properties of the synthetic copper mineral engelhauptite, $mathrm{KC}{mathrm{u}}_{3}{mathrm{V}}_{2}{mathrm{O}}_{7}{(mathrm{OH})}_{2}mathrm{Cl}$, which possesses a kagome lattice made of $mathrm{C}{mathrm{u}}^{2+}$ ($3{d}^{9}$) ions. Unlike the hexagonal structure with a perfect kagome lattice reported in the natural mineral, a synthetic crystal has a monoclinic structure with a distorted kagome lattice. We observe a magnetic transition at 6 K and an anomaly in the magnetization curve around 50 T. Engelhauptite represents a variant of the $S=1/2$ kagome antiferromagnet and we discuss the structure-property relationship by comparing engelhauptite and its relative compound volborthite, $mathrm{C}{mathrm{u}}_{3}{mathrm{V}}_{2}{mathrm{O}}_{7}{(mathrm{OH})}_{2}ifmmodecdotelsetextperiodcenteredfi{}2{mathrm{H}}_{2}mathrm{O}$." @default.
- W2953707911 created "2019-07-12" @default.
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- W2953707911 date "2019-06-26" @default.
- W2953707911 modified "2023-10-17" @default.
- W2953707911 title "Engelhauptite: A variant of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>S</mml:mi><mml:mo>=</mml:mo><mml:mfrac><mml:mn>1</mml:mn><mml:mn>2</mml:mn></mml:mfrac></mml:mrow></mml:math> kagome antiferromagnet" @default.
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- W2953707911 doi "https://doi.org/10.1103/physrevmaterials.3.064414" @default.
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