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- W2953738768 startingPage "111281" @default.
- W2953738768 abstract "This study introduces a novel and effective inhibition system based on Persian Echium amoenum (PEA) and zinc nitrate for mild steel protection in 3.5 wt% NaCl solution. The functional groups and complexes in the structure of PEA and PEA:Zn containing solutions were surveyed by UV–Vis analysis. The composition and morphology examination of surficial films were carried out by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), atomic force microscope (AFM), nuclear magnetic resonance spectroscopy (NMR), grazing incidence X-ray diffraction (GIXRD) analysis, and static contact angle (CA) measurements. Electrochemical impedance spectroscopy (EIS) and potentiodynamic spectroscopy (PDS) were carried out to study the performance of each PEA:Zn ratios and understand the mechanism of inhibition. Moreover, the computational studies were utilized to have a better conception from the mechanism of chelation. Results of electrochemical analyses showed that the 200 ppm PEA +600 ppm Zn sample has the highest performance and efficiency (95%). Moreover, the electronic-scale quantum mechanics (QM) computations proposed the donor-acceptor interactions of inhibiting species with the metallic surface. This means that the protective PEA-Fe-Zn complexes have been formed through the injection of the lone pair electrons of organic structures into the empty d-orbitals of the metallic ions of Zn and Fe." @default.
- W2953738768 created "2019-07-12" @default.
- W2953738768 creator A5018247556 @default.
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- W2953738768 creator A5061776373 @default.
- W2953738768 date "2019-10-01" @default.
- W2953738768 modified "2023-10-09" @default.
- W2953738768 title "A green complex film based on the extract of Persian Echium amoenum and zinc nitrate for mild steel protection in saline solution; Electrochemical and surface explorations besides dynamic simulation" @default.
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- W2953738768 doi "https://doi.org/10.1016/j.molliq.2019.111281" @default.
- W2953738768 hasPublicationYear "2019" @default.