Matches in SemOpenAlex for { <https://semopenalex.org/work/W2953797811> ?p ?o ?g. }
- W2953797811 endingPage "3489" @default.
- W2953797811 startingPage "3481" @default.
- W2953797811 abstract "The orthopalladation of ( Z )‐4‐arylidene‐5(4 H )‐oxazolones ( 1a – 1o ), with electron‐withdrawing substituents (Cl, F, CF 3 ) in the 4‐arylidene ring has been carried out by C–H bond activation. The process is regioselective and only the ortho C–H bond of the 4‐arylidene ring is activated. The orthopalladated complexes ( 2a – 2o ) have different structures (mono‐, di‐ and trinuclear), although the dinuclear open‐book scaffold, in which the C=C bonds of the arylidene group are in a face‐to‐face transoid arrangement, is prevalent. Irradiation of 2a – 2n with blue light promotes the C–C coupling by [2+2]‐photocycloaddition of the arylidene C=C bonds and the formation of the dinuclear cyclobutanes ( 3a – 3n ). The oxidation of cyclobutane 3d with PhICl 2 or Br 2 occurs with halogenation of the Pd–C bond and release of the ortho ‐halogenated dispirocyclobutane, which can be converted into the ortho ‐halo‐1,3‐diaminotruxillic derivatives ( 5d , 6d , 7d ) by oxazolone ring opening in a basic medium." @default.
- W2953797811 created "2019-07-12" @default.
- W2953797811 creator A5021125291 @default.
- W2953797811 creator A5024529120 @default.
- W2953797811 creator A5083225216 @default.
- W2953797811 creator A5083990663 @default.
- W2953797811 date "2019-07-12" @default.
- W2953797811 modified "2023-10-01" @default.
- W2953797811 title "Functionalized 1,3‐Diaminotruxillic Acids by Pd‐Mediated C–H Activation and [2+2]‐Photocycloaddition of 5(4 <i>H</i> )‐Oxazolones" @default.
- W2953797811 cites W1598759915 @default.
- W2953797811 cites W1919168988 @default.
- W2953797811 cites W1956040901 @default.
- W2953797811 cites W1967475183 @default.
- W2953797811 cites W1973786313 @default.
- W2953797811 cites W1974196996 @default.
- W2953797811 cites W1981055366 @default.
- W2953797811 cites W1982032801 @default.
- W2953797811 cites W1988501547 @default.
- W2953797811 cites W1989824322 @default.
- W2953797811 cites W1993298831 @default.
- W2953797811 cites W1997608145 @default.
- W2953797811 cites W1999082957 @default.
- W2953797811 cites W2002740475 @default.
- W2953797811 cites W2004248055 @default.
- W2953797811 cites W2007784335 @default.
- W2953797811 cites W2010997966 @default.
- W2953797811 cites W2013276134 @default.
- W2953797811 cites W2015211157 @default.
- W2953797811 cites W2020442935 @default.
- W2953797811 cites W2022793501 @default.
- W2953797811 cites W2026228805 @default.
- W2953797811 cites W2028990075 @default.
- W2953797811 cites W2034701671 @default.
- W2953797811 cites W2038452922 @default.
- W2953797811 cites W2042953778 @default.
- W2953797811 cites W2045596332 @default.
- W2953797811 cites W2045813667 @default.
- W2953797811 cites W2053202019 @default.
- W2953797811 cites W2056422685 @default.
- W2953797811 cites W2056637308 @default.
- W2953797811 cites W2057539318 @default.
- W2953797811 cites W2057639794 @default.
- W2953797811 cites W2061837305 @default.
- W2953797811 cites W2071341313 @default.
- W2953797811 cites W2071765830 @default.
- W2953797811 cites W2074313351 @default.
- W2953797811 cites W2074991934 @default.
- W2953797811 cites W2079083612 @default.
- W2953797811 cites W2085073123 @default.
- W2953797811 cites W2093731515 @default.
- W2953797811 cites W2093915146 @default.
- W2953797811 cites W2096943508 @default.
- W2953797811 cites W2097573795 @default.
- W2953797811 cites W2099531933 @default.
- W2953797811 cites W2114481902 @default.
- W2953797811 cites W2122480383 @default.
- W2953797811 cites W2131350133 @default.
- W2953797811 cites W2139532113 @default.
- W2953797811 cites W2142653506 @default.
- W2953797811 cites W2148066840 @default.
- W2953797811 cites W2151416474 @default.
- W2953797811 cites W2153387011 @default.
- W2953797811 cites W2170320292 @default.
- W2953797811 cites W2175189736 @default.
- W2953797811 cites W2314473542 @default.
- W2953797811 cites W2314698653 @default.
- W2953797811 cites W2315098968 @default.
- W2953797811 cites W2322699185 @default.
- W2953797811 cites W2323381394 @default.
- W2953797811 cites W2326384597 @default.
- W2953797811 cites W2330872607 @default.
- W2953797811 cites W2331283941 @default.
- W2953797811 cites W2339051409 @default.
- W2953797811 cites W2342892827 @default.
- W2953797811 cites W2528107622 @default.
- W2953797811 cites W2743283092 @default.
- W2953797811 cites W2765493935 @default.
- W2953797811 cites W2777067454 @default.
- W2953797811 cites W2894769665 @default.
- W2953797811 cites W2950545306 @default.
- W2953797811 cites W4238711828 @default.
- W2953797811 cites W4253538357 @default.
- W2953797811 cites W4255374517 @default.
- W2953797811 doi "https://doi.org/10.1002/ejic.201900548" @default.
- W2953797811 hasPublicationYear "2019" @default.
- W2953797811 type Work @default.
- W2953797811 sameAs 2953797811 @default.
- W2953797811 citedByCount "7" @default.
- W2953797811 countsByYear W29537978112020 @default.
- W2953797811 countsByYear W29537978112021 @default.
- W2953797811 countsByYear W29537978112022 @default.
- W2953797811 countsByYear W29537978112023 @default.
- W2953797811 crossrefType "journal-article" @default.
- W2953797811 hasAuthorship W2953797811A5021125291 @default.
- W2953797811 hasAuthorship W2953797811A5024529120 @default.
- W2953797811 hasAuthorship W2953797811A5083225216 @default.
- W2953797811 hasAuthorship W2953797811A5083990663 @default.
- W2953797811 hasConcept C155647269 @default.