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- W2954163683 abstract "A general [4 + 1] cyclization reaction of carbonyl nucleophiles with 2-iodomethylallyl peroxides, which function as unique electrophilic oxygen synthons, for the synthesis of a broad range of 2,2-disubstituted tetrahydrofurans is achieved under operationally simple conditions. The unprecedented asymmetric version of such reaction is also realized via chiral auxiliary-assisted cyclization, thus providing a distinct approach to access chiral tetrahydrofurans with high diastereoselectivities. The new method can be applied to the synthesis of core structure of posaconazole drug." @default.
- W2954163683 created "2019-07-12" @default.
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- W2954163683 date "2019-07-05" @default.
- W2954163683 modified "2023-10-18" @default.
- W2954163683 title "General [4 + 1] Cyclization Approach To Access 2,2-Disubstituted Tetrahydrofurans Enabled by Electrophilic Bifunctional Peroxides" @default.
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- W2954163683 doi "https://doi.org/10.1021/acs.orglett.9b02012" @default.
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