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• W2954372345 endingPage "121739" @default.
• W2954372345 startingPage "121739" @default.
• W2954372345 abstract "To explore fast pyrolysis behaviors of cedar biomass, the infrared heating technique with quick heating rate was taken in a fixed-bed reactor. The effects of heating rates (5–30 °C/s) and pyrolysis temperatures (400–600 °C) on pyrolysis products distribution and compositions were discussed, and the reaction mechanism was proposed. The results show that high heating rate can significantly suppress secondary reaction of primary volatiles. GC/FID and GC/MS analyses indicate that higher heating rate is favorable to the generation of glucose derivatives such as acids and furans. However, higher temperature can obviously promote further conversion of guaiacyl-contained structure following demethylation, demethoxylation and H/CH3 assisted demethoxylation routes, which were proposed to interpret the formation of biphenolic hydroxyl and monophenolic hydroxyl compounds such as phenol, 2-methyl-phenol and 2,4-dimethyl-phenol, respectively. Moreover, the demethylation route exhibits obvious conversion advantage at higher temperature due to lower energy barrier." @default.
• W2954372345 created "2019-07-12" @default.
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• W2954372345 date "2019-10-01" @default.
• W2954372345 modified "2023-10-16" @default.
• W2954372345 title "Fast pyrolysis behaviors of cedar in an infrared-heated fixed-bed reactor" @default.
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• W2954372345 doi "https://doi.org/10.1016/j.biortech.2019.121739" @default.
• W2954372345 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31302467" @default.
• W2954372345 hasPublicationYear "2019" @default.
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