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• W2954426525 abstract "Sulfur‐resistant methanation of syngas was studied over MoO 3 –ZrO 2 catalysts at 400°C. The MoO 3 –ZrO 2 solid‐solution catalysts were prepared using the solution combustion method by varying MoO 3 content and temperature. The 15MoO 3 –ZrO 2 catalyst achieved the highest methanation performance with CO conversion up to 80% at 400°C. The structure of ZrO 2 and dispersed MoO 3 species was characterized using X‐ray diffraction and transmission electron microscopy. The energy‐dispersive spectrum of the 15MoO 3 –ZrO 2 catalyst showed that the solution combustion method gave well‐dispersed MoO 3 particles on the surface of ZrO 2 . The structure of the catalysts depends on the Mo surface density. It was observed that in the 15MoO 3 –ZrO 2 catalyst the Mo surface density of 4.2 Mo atoms nm −2 approaches the theoretical monolayer capacity of 5 Mo atoms nm −2 . The addition of a small amount of MoO 3 to ZrO 2 led to higher tetragonal content of ZrO 2 along with a reduction of particle size. This leads to an efficient catalyst for the low‐temperature CO methanation process." @default.
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• W2954426525 date "2019-07-01" @default.
• W2954426525 modified "2023-10-16" @default.
• W2954426525 title "Enhanced sulfur‐resistant methanation performance over MoO ₃ –ZrO ₂ catalyst prepared by solution combustion method" @default.
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• W2954426525 doi "https://doi.org/10.1002/aoc.5022" @default.
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