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• W2954728388 abstract "Chiral silica, which acts as a nucleating agent of poly(ε-caprolactone) (PCL), was demonstrated to induce excess handedness of lamellar twist in the banded spherulites of PCL blended with poly(vinyl butyral). The d- and l-forms of silica enhanced the right- and left-handed twists, respectively. The influences of chiral silica on the twist handedness were statistically significant. These results indicate that the handedness of twisting can be controlled upon primary nucleation. The organic substances used as chiral templates of silica had no effect on the handedness; silica was shown to govern the handedness. The possible mechanisms of the chirality transfer are discussed." @default.
• W2954728388 created "2019-07-12" @default.
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• W2954728388 date "2019-06-28" @default.
• W2954728388 modified "2023-09-24" @default.
• W2954728388 title "Chiral Nucleating Agents Affecting the Handedness of Lamellar Twist in the Banded Spherulites in Poly(ε-Caprolactone)/Poly(Vinyl Butyral) Blends" @default.
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• W2954728388 doi "https://doi.org/10.1021/acsmacrolett.9b00416" @default.
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