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• W2954882262 endingPage "4290" @default.
• W2954882262 startingPage "4286" @default.
• W2954882262 abstract "Abstract A palladium(II)‐functionalized covalent organic framework (Pd@TpBpy COF) constructed from 1,3,5‐triformylphloroglucinol (Tp) and [2,2′‐bipyridine]‐5,5′‐diamine (Bpy) is reported as a recyclable catalyst for conjugate additions in aqueous media. Additions of an array of stereoelectronically diverse arylboronic acid nucleophiles to β,β‐disubstituted enones form a variety of ketones containing benzylic all‐carbon quaternary centers in up to 92 % isolated yield. Studies on the recyclability of Pd@TpBpy COF show this catalyst remains active through at least 7 cycles and shows superior stability to related MOF catalysts with bipyridine linker units." @default.
• W2954882262 created "2019-07-12" @default.
• W2954882262 creator A5024717098 @default.
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• W2954882262 date "2019-08-08" @default.
• W2954882262 modified "2023-10-17" @default.
• W2954882262 title "A Pd(II)‐Functionalized Covalent Organic Framework for Catalytic Conjugate Additions of Arylboronic Acids to β,β‐Disubstituted Enones" @default.
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• W2954882262 doi "https://doi.org/10.1002/cctc.201900894" @default.
• W2954882262 hasPublicationYear "2019" @default.
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