FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2954901829> ?p ?o ?g. }

• W2954901829 endingPage "4537" @default.
• W2954901829 startingPage "4526" @default.
• W2954901829 abstract "Here we report the dynamics of organic cations as guest molecules in the novel perovskite host framework. The novel switchable crystals from the coordination family [CH3C(NH2)2]2[KB″(CN)6] were constructed by employing acetamidinium cations (ACE = [CH3C(NH2)2]) as A-site and B″: Cr3+, Fe3+, Co3+ in the inorganic cage. The molecular motion of ACE+ as well as the effect of the trivalent metallic cation type on two-step transitions were studied using a combination of experimental methods: (i) X-ray diffraction experiments, (ii) thermal analysis, (iii) dielectric and electric studies, (iv) optical observations, (v) 1H NMR spectroscopy, and (vi) quasielastic neutron scattering (QENS). On the basis of the X-ray analysis, transitions occur from a frozen-order phase (III, monoclinic, C2/m) to an in-plane rotational disorder state (II, trigonal, R3̅m) and to a melt-like disorder one (I, cubic, Fm3̅m). A markedly temperature-dependent dielectric constant indicates the tunable and switchable properties of all complexes. The QENS, as well as 1H NMR spectroscopy, were applied to measure the dynamics of the organic cations residing in the inorganic framework. The ferroelastic nature of the phases III and II were proven based on the polarized light microscopy photographs. Also, the modified equation of the tolerance factor t was used to estimate the theoretical phase transition temperatures for a crystal with Mn3+." @default.
• W2954901829 created "2019-07-12" @default.
• W2954901829 creator A5023247528 @default.
• W2954901829 creator A5037021694 @default.
• W2954901829 creator A5038907801 @default.
• W2954901829 creator A5051383988 @default.
• W2954901829 creator A5065562848 @default.
• W2954901829 creator A5074985937 @default.
• W2954901829 creator A5078381258 @default.
• W2954901829 date "2019-06-24" @default.
• W2954901829 modified "2023-10-14" @default.
• W2954901829 title "Screening Ferroelastic Transitions in Switchable Cyano-Bridged Perovskites: [CH₃C(NH₂)₂]₂[KM(CN)₆], M = Cr³⁺, Fe³⁺, Co³⁺. Crystal Structure Characterization, Dielectric Properties, ¹H NMR, and Quasielastic Neutron Scattering Studies" @default.
• W2954901829 cites W1860287188 @default.
• W2954901829 cites W1949665973 @default.
• W2954901829 cites W1966193248 @default.
• W2954901829 cites W1972590175 @default.
• W2954901829 cites W1976775143 @default.
• W2954901829 cites W1977897877 @default.
• W2954901829 cites W1988177701 @default.
• W2954901829 cites W1992295247 @default.
• W2954901829 cites W1992587100 @default.
• W2954901829 cites W1999679917 @default.
• W2954901829 cites W2008922772 @default.
• W2954901829 cites W2009295266 @default.
• W2954901829 cites W2021630428 @default.
• W2954901829 cites W2028645911 @default.
• W2954901829 cites W2041726686 @default.
• W2954901829 cites W2050694134 @default.
• W2954901829 cites W2059841912 @default.
• W2954901829 cites W2063871837 @default.
• W2954901829 cites W2064744796 @default.
• W2954901829 cites W2070336723 @default.
• W2954901829 cites W2074766293 @default.
• W2954901829 cites W2078936921 @default.
• W2954901829 cites W2087951769 @default.
• W2954901829 cites W2122179865 @default.
• W2954901829 cites W2124141328 @default.
• W2954901829 cites W2131350133 @default.
• W2954901829 cites W2131904845 @default.
• W2954901829 cites W2134917423 @default.
• W2954901829 cites W2139755213 @default.
• W2954901829 cites W2212415466 @default.
• W2954901829 cites W2236321905 @default.
• W2954901829 cites W2264700389 @default.
• W2954901829 cites W2275507030 @default.
• W2954901829 cites W2313570818 @default.
• W2954901829 cites W2317434972 @default.
• W2954901829 cites W2329852642 @default.
• W2954901829 cites W2332002849 @default.
• W2954901829 cites W2345279020 @default.
• W2954901829 cites W2525372591 @default.
• W2954901829 cites W2547812488 @default.
• W2954901829 cites W2575945368 @default.
• W2954901829 cites W2586930867 @default.
• W2954901829 cites W2606996551 @default.
• W2954901829 cites W2791098460 @default.
• W2954901829 cites W2809084553 @default.
• W2954901829 cites W2883851948 @default.
• W2954901829 cites W2901364126 @default.
• W2954901829 cites W3102237102 @default.
• W2954901829 doi "https://doi.org/10.1021/acs.cgd.9b00298" @default.
• W2954901829 hasPublicationYear "2019" @default.
• W2954901829 type Work @default.
• W2954901829 sameAs 2954901829 @default.
• W2954901829 citedByCount "18" @default.
• W2954901829 countsByYear W29549018292019 @default.
• W2954901829 countsByYear W29549018292020 @default.
• W2954901829 countsByYear W29549018292021 @default.
• W2954901829 countsByYear W29549018292022 @default.
• W2954901829 countsByYear W29549018292023 @default.
• W2954901829 crossrefType "journal-article" @default.
• W2954901829 hasAuthorship W2954901829A5023247528 @default.
• W2954901829 hasAuthorship W2954901829A5037021694 @default.
• W2954901829 hasAuthorship W2954901829A5038907801 @default.
• W2954901829 hasAuthorship W2954901829A5051383988 @default.
• W2954901829 hasAuthorship W2954901829A5065562848 @default.
• W2954901829 hasAuthorship W2954901829A5074985937 @default.
• W2954901829 hasAuthorship W2954901829A5078381258 @default.
• W2954901829 hasConcept C104015590 @default.
• W2954901829 hasConcept C113196181 @default.
• W2954901829 hasConcept C115624301 @default.
• W2954901829 hasConcept C116306529 @default.
• W2954901829 hasConcept C120665830 @default.
• W2954901829 hasConcept C121332964 @default.
• W2954901829 hasConcept C133386390 @default.
• W2954901829 hasConcept C149288129 @default.
• W2954901829 hasConcept C155011858 @default.
• W2954901829 hasConcept C185592680 @default.
• W2954901829 hasConcept C191486275 @default.
• W2954901829 hasConcept C192562407 @default.
• W2954901829 hasConcept C26873012 @default.
• W2954901829 hasConcept C31198834 @default.
• W2954901829 hasConcept C32891209 @default.
• W2954901829 hasConcept C43617362 @default.
• W2954901829 hasConcept C49040817 @default.
• W2954901829 hasConcept C61276311 @default.
• W2954901829 hasConcept C62520636 @default.
• W2954901829 hasConcept C73585123 @default.

• next