Matches in SemOpenAlex for { <https://semopenalex.org/work/W2954902240> ?p ?o ?g. }
- W2954902240 endingPage "9353" @default.
- W2954902240 startingPage "9346" @default.
- W2954902240 abstract "We demonstrate the application of implanted-ion β-detected NMR as a probe of ionic liquid molecular dynamics through the measurement of 8Li spin-lattice relaxation (SLR) and resonance in 1-ethyl-3-methylimidazolium acetate. The motional narrowing of the resonance and the local maxima in the SLR rate, 1/T1, imply sensitivity to subnanosecond Li+ solvation dynamics. From an analysis of 1/T1, we extract an activation energy EA = 74.8(1.5) meV and Vogel–Fulcher–Tammann constant TVFT = 165.8(0.9) K, in agreement with the dynamic viscosity of the bulk solvent. Near the melting point, the lineshape is broad and intense, and the form of the relaxation is nonexponential, reflective of our sensitivity to heterogeneous dynamics near the glass transition. The depth resolution of this technique may later provide a unique means of studying nanoscale phenomena in ionic liquids." @default.
- W2954902240 created "2019-07-12" @default.
- W2954902240 creator A5015677736 @default.
- W2954902240 creator A5017691605 @default.
- W2954902240 creator A5017930902 @default.
- W2954902240 creator A5021092481 @default.
- W2954902240 creator A5030759641 @default.
- W2954902240 creator A5031999024 @default.
- W2954902240 creator A5033340669 @default.
- W2954902240 creator A5039614423 @default.
- W2954902240 creator A5048008319 @default.
- W2954902240 creator A5054818798 @default.
- W2954902240 creator A5055420269 @default.
- W2954902240 creator A5065523228 @default.
- W2954902240 creator A5065665606 @default.
- W2954902240 creator A5069964985 @default.
- W2954902240 creator A5070714748 @default.
- W2954902240 creator A5075456590 @default.
- W2954902240 creator A5082660511 @default.
- W2954902240 date "2019-11-12" @default.
- W2954902240 modified "2023-10-17" @default.
- W2954902240 title "Dynamics of Liquid 1-Ethyl-3-Methylimidazolium Acetate Measured with Implanted-Ion <sup>8</sup>Li β-NMR" @default.
- W2954902240 cites W121751167 @default.
- W2954902240 cites W1561625864 @default.
- W2954902240 cites W1761109852 @default.
- W2954902240 cites W1965200916 @default.
- W2954902240 cites W1969516420 @default.
- W2954902240 cites W1974873169 @default.
- W2954902240 cites W1974930704 @default.
- W2954902240 cites W1978821082 @default.
- W2954902240 cites W1982295742 @default.
- W2954902240 cites W1982381330 @default.
- W2954902240 cites W1986719868 @default.
- W2954902240 cites W1987127228 @default.
- W2954902240 cites W1990049255 @default.
- W2954902240 cites W1990944523 @default.
- W2954902240 cites W1991531781 @default.
- W2954902240 cites W1999241227 @default.
- W2954902240 cites W2006067388 @default.
- W2954902240 cites W2010478558 @default.
- W2954902240 cites W2013557509 @default.
- W2954902240 cites W2016249662 @default.
- W2954902240 cites W2021641921 @default.
- W2954902240 cites W2024585900 @default.
- W2954902240 cites W2024708524 @default.
- W2954902240 cites W2026899226 @default.
- W2954902240 cites W2029368235 @default.
- W2954902240 cites W2033376841 @default.
- W2954902240 cites W2034875509 @default.
- W2954902240 cites W2037817420 @default.
- W2954902240 cites W2048576969 @default.
- W2954902240 cites W2048995035 @default.
- W2954902240 cites W2052185182 @default.
- W2954902240 cites W2053471085 @default.
- W2954902240 cites W2060151241 @default.
- W2954902240 cites W2063407634 @default.
- W2954902240 cites W2063695143 @default.
- W2954902240 cites W2064367026 @default.
- W2954902240 cites W2079275160 @default.
- W2954902240 cites W2081688282 @default.
- W2954902240 cites W2084761689 @default.
- W2954902240 cites W2087145580 @default.
- W2954902240 cites W2088103961 @default.
- W2954902240 cites W2090225338 @default.
- W2954902240 cites W2090636324 @default.
- W2954902240 cites W2091065846 @default.
- W2954902240 cites W2091570098 @default.
- W2954902240 cites W2097952819 @default.
- W2954902240 cites W2124302857 @default.
- W2954902240 cites W2127632630 @default.
- W2954902240 cites W2131904845 @default.
- W2954902240 cites W2168258097 @default.
- W2954902240 cites W2248278631 @default.
- W2954902240 cites W2255691696 @default.
- W2954902240 cites W2301085974 @default.
- W2954902240 cites W2313736793 @default.
- W2954902240 cites W2316301857 @default.
- W2954902240 cites W2317957732 @default.
- W2954902240 cites W2323970473 @default.
- W2954902240 cites W2368241538 @default.
- W2954902240 cites W2430404605 @default.
- W2954902240 cites W2487893342 @default.
- W2954902240 cites W2506037955 @default.
- W2954902240 cites W2565875091 @default.
- W2954902240 cites W2592355000 @default.
- W2954902240 cites W2725392338 @default.
- W2954902240 cites W2787042986 @default.
- W2954902240 cites W2804869904 @default.
- W2954902240 cites W284548676 @default.
- W2954902240 cites W2886658373 @default.
- W2954902240 cites W2892201138 @default.
- W2954902240 cites W2895141304 @default.
- W2954902240 cites W2904667474 @default.
- W2954902240 cites W4245041823 @default.
- W2954902240 doi "https://doi.org/10.1021/acs.chemmater.9b02864" @default.
- W2954902240 hasPublicationYear "2019" @default.
- W2954902240 type Work @default.
- W2954902240 sameAs 2954902240 @default.