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• W2954989541 startingPage "1065" @default.
• W2954989541 abstract "Aminobenzoic acid derivatives are widely used in the preparation of new coordination polymers since they contain O-atom donors, as well as N-atom donors, and have a rich variety of coordination modes which can lead to polymers with intriguing structures and interesting properties. Two new coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid (H 3 abtc), namely, poly[(μ 3 -1-amino-5-carboxybenzene-3,4-dicarboxylato)diaquacadmium(II)], [Cd(C 9 H 5 NO 6 )(H 2 O) 2 ] n , (I), and poly[[bis(μ 5 -1-aminobenzene-3,4,5-tricarboxylato)triaquatrizinc(II)] dihydrate], {[Zn 3 (C 9 H 4 NO 6 ) 2 (H 2 O) 3 ]·2H 2 O} n , (II), have been prepared and structurally characterized by single-crystal X-ray diffraction. In polymer (I), each tridentate 1-amino-5-carboxybenzene-3,4-dicarboxylate (Habtc 2− ) ligand coordinates to three Cd II ions to form a two-dimensional network structure, in which all of the Cd II ions and Habtc 2− ligands are equivalent, respectively. Polymer (II) also exhibits a two-dimensional network structure, in which three crystallographically independent Zn II ions are bridged by two crystallographically independent pentadentate 1-aminobenzene-3,4,5-tricarboxylate (abtc 3− ) ligands. This indicates that changing the metal ion can influence the coordination mode of the H 3 abtc-derived ligand and further influence the detailed architecture of the polymer. Moreover, the IR spectra, thermogravimetric analyses and fluorescence properties were investigated." @default.
• W2954989541 created "2019-07-12" @default.
• W2954989541 creator A5008573470 @default.
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• W2954989541 date "2019-07-05" @default.
• W2954989541 modified "2023-09-24" @default.
• W2954989541 title "Two new Cd^II and Zn^II coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid: synthesis, crystal structure and characterization" @default.
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• W2954989541 doi "https://doi.org/10.1107/s2053229619009227" @default.
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