FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2955132371> ?p ?o ?g. }

• W2955132371 endingPage "8822" @default.
• W2955132371 startingPage "8813" @default.
• W2955132371 abstract "Methyl bromide (CH3Br) and methyl chloride (CH3Cl) significantly contribute to stratospheric ozone depletion. The atmospheric budgets of both compounds are unbalanced with known degradation processes outweighing known emissions. Stable isotope analysis may be capable to identify and quantify emissions and to achieve a balanced budget. Degradation processes do, however, cause isotope fractionation in methyl halides after emission and hence knowledge about these processes is a crucial prerequisite for any isotopic mass balance approach. In the current study, triple-element isotope analysis (2H, 13C, 37Cl/81Br) was applied to investigate the two main abiotic degradation processes of methyl halides (CH3X) in fresh and seawater: hydrolysis and halide exchange. For CH3Br, nucleophilic attack by both H2O and Cl– caused significant primary carbon and bromine isotope effects accompanied by a secondary inverse hydrogen isotope effect. For CH3Cl only nucleophilic substitution by H2O was observed at significant rates causing large primary carbon and chlorine isotope effects and a secondary inverse hydrogen isotope effect. Observed dual-element isotope ratios differed slightly from literature values for microbial degradation in water and hugely from radical reactions in the troposphere. This bodes well for successfully distinguishing and quantifying degradation processes in atmospheric methyl halides using triple-element isotope analysis." @default.
• W2955132371 created "2019-07-12" @default.
• W2955132371 creator A5001042804 @default.
• W2955132371 creator A5009760942 @default.
• W2955132371 creator A5024928583 @default.
• W2955132371 creator A5048356903 @default.
• W2955132371 date "2019-06-25" @default.
• W2955132371 modified "2023-10-09" @default.
• W2955132371 title "Isotopic Characterization (²H, ¹³C, ³⁷Cl, ⁸¹Br) of Abiotic Degradation of Methyl Bromide and Methyl Chloride in Water and Implications for Future Studies" @default.
• W2955132371 cites W1492486543 @default.
• W2955132371 cites W1585609718 @default.
• W2955132371 cites W1965055433 @default.
• W2955132371 cites W1968345919 @default.
• W2955132371 cites W1980995154 @default.
• W2955132371 cites W1984302197 @default.
• W2955132371 cites W1986843376 @default.
• W2955132371 cites W1986941221 @default.
• W2955132371 cites W1996909816 @default.
• W2955132371 cites W1998123511 @default.
• W2955132371 cites W1998224773 @default.
• W2955132371 cites W2002022320 @default.
• W2955132371 cites W2004748396 @default.
• W2955132371 cites W2008671817 @default.
• W2955132371 cites W2009006705 @default.
• W2955132371 cites W2013932933 @default.
• W2955132371 cites W2014341431 @default.
• W2955132371 cites W2023962760 @default.
• W2955132371 cites W2026057947 @default.
• W2955132371 cites W2026229574 @default.
• W2955132371 cites W2035962480 @default.
• W2955132371 cites W2036247488 @default.
• W2955132371 cites W2040900558 @default.
• W2955132371 cites W2046332202 @default.
• W2955132371 cites W2048795853 @default.
• W2955132371 cites W2051922773 @default.
• W2955132371 cites W2054694478 @default.
• W2955132371 cites W2057569279 @default.
• W2955132371 cites W2059633540 @default.
• W2955132371 cites W2060576106 @default.
• W2955132371 cites W2063441688 @default.
• W2955132371 cites W2064289896 @default.
• W2955132371 cites W2068312108 @default.
• W2955132371 cites W2075161563 @default.
• W2955132371 cites W2075480037 @default.
• W2955132371 cites W2095715736 @default.
• W2955132371 cites W2096906074 @default.
• W2955132371 cites W2111639786 @default.
• W2955132371 cites W2128866213 @default.
• W2955132371 cites W2136723979 @default.
• W2955132371 cites W2150818639 @default.
• W2955132371 cites W2157281157 @default.
• W2955132371 cites W2161383527 @default.
• W2955132371 cites W2166676193 @default.
• W2955132371 cites W2168960627 @default.
• W2955132371 cites W2171976453 @default.
• W2955132371 cites W2279182020 @default.
• W2955132371 cites W2291674210 @default.
• W2955132371 cites W2325027988 @default.
• W2955132371 cites W2464792389 @default.
• W2955132371 cites W2746284685 @default.
• W2955132371 cites W2750141380 @default.
• W2955132371 cites W2759859368 @default.
• W2955132371 cites W2769834416 @default.
• W2955132371 cites W2783143476 @default.
• W2955132371 cites W2783716976 @default.
• W2955132371 cites W2788849571 @default.
• W2955132371 cites W2791047223 @default.
• W2955132371 cites W2802281438 @default.
• W2955132371 cites W2890673895 @default.
• W2955132371 cites W2950386231 @default.
• W2955132371 doi "https://doi.org/10.1021/acs.est.9b02165" @default.
• W2955132371 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31286766" @default.
• W2955132371 hasPublicationYear "2019" @default.
• W2955132371 type Work @default.
• W2955132371 sameAs 2955132371 @default.
• W2955132371 citedByCount "15" @default.
• W2955132371 countsByYear W29551323712019 @default.
• W2955132371 countsByYear W29551323712020 @default.
• W2955132371 countsByYear W29551323712021 @default.
• W2955132371 countsByYear W29551323712022 @default.
• W2955132371 countsByYear W29551323712023 @default.
• W2955132371 crossrefType "journal-article" @default.
• W2955132371 hasAuthorship W2955132371A5001042804 @default.
• W2955132371 hasAuthorship W2955132371A5009760942 @default.
• W2955132371 hasAuthorship W2955132371A5024928583 @default.
• W2955132371 hasAuthorship W2955132371A5048356903 @default.
• W2955132371 hasBestOaLocation W29551323712 @default.
• W2955132371 hasConcept C107872376 @default.
• W2955132371 hasConcept C111368507 @default.
• W2955132371 hasConcept C121332964 @default.
• W2955132371 hasConcept C125047889 @default.
• W2955132371 hasConcept C127313418 @default.
• W2955132371 hasConcept C155647269 @default.
• W2955132371 hasConcept C171560689 @default.
• W2955132371 hasConcept C178790620 @default.
• W2955132371 hasConcept C179104552 @default.
• W2955132371 hasConcept C185592680 @default.
• W2955132371 hasConcept C22117777 @default.

• next